SUPPLEMENTAL INVESTIGATION
ADDENDUM REPORT
NON-PUBLIC PROPERTIES STUDY
AREA
Prepared for:
![]()
OLIN CORPORATION
March 2006
Environmental ENGINEERS, SCIENTISTS
& PLANNERS
TABLE OF CONTENTS
Section Page
2.0 SUPPLEMENTAL INVESTIGATION SCOPE OF
WORK
2.1 CONTIGUOUS
FILL ASSESSMENT
3.1 MODIFICATIONS
TO THE CONCEPTUAL SITE MODEL
3.2 CONTIGUOUS
FILL DELINEATION
3.2.1 Block E – Newhall Street Area
3.2.1.1 1048
Winchester Avenue
3.2.2 Block J – Southwest Satellite Area
3.2.2.1 293 and
297 Goodrich Street
3.2.2.2 300 and
304 Morse Street
3.2.3 Block L – Southwest Satellite Area
3.2.4 Block Q – Newhall Street Area
3.2.5 Block T – Augur Street Area
3.2.5.2 13 and 17
Harris Street
3.4 RIGHT-OF-WAY
CONFIRMATION BORINGS
List of Tables - Microsoft Excel required to open and read the files.
2-1 Investigation Activities by
Parcel
NOTE: Tables 3-2 through 3-10, listed below, are all in the same file, Tables 3-2 to 3-10.xls
3-2 SW Satellite Area Analytical Data Summary (Microsoft Excel Document)
3-6 Isolated Fill Analytical Data Summary (Microsoft Excel Document)
3-7 Ambient Sample Analytical Data Summary (Microsoft Excel Document)
3-8 Non-compliant Samples for Only Non-Principal SOCs (Microsoft Excel Document)
3-9 Properties Outside Contiguous Fill – Rationale for Investigation (Microsoft Excel Document)
3-10 May 2005 Isolated Fill Sample Descriptions (Microsoft Excel Document)
5-10 No Fill Properties List by Address (Microsoft Excel Document)
SHEETS
Back Pockets
All files below are PDFs. Any PDF greater than 1MB in file size is indicated, and will require a long download time. Please be patient!
Sheet 2 Extent and Thickness of Fill (Blocks C through S) (3MB)
Sheet 3 Extent and Thickness of Fill (Block T)
Sheet 4 Principal Substances of Concern in Fill (7.5MB)
Sheet 5 Principal Substances of Concern in Soil (7.1MB)
Sheet 10 Remedial Alternatives (1.6MB)
APPENDICES
Stratigraphic Database.......................................................................................................... C
X-Ray Fluorescence Data & Evaluation................................................................................. E
Fill Area Volume Calculations ............................................................................................... F
Soil/Fill Sample Analyses...................................................................................................... G
Soil/Fill Sample Analytical Results......................................................................................... H
Laboratory Analytical
Results and Data Validation Reports..................................................... I
Town of Hamden Storm Drain Plan........................................................................................ J (no electronic version available)
DOCUMENT
CERTIFICATION
I have personally examined and am familiar with the information submitted in this document and all attachments thereto, and I certify, based on reasonable investigation, including my inquiry of those individuals responsible for obtaining the information, that the submitted information is true, accurate and complete to the best of my knowledge and belief. I understand that any false statement made in the submitted information is punishable as a criminal offense under §53a-157b of the Connecticut General Statutes and any other applicable law.
_______________________________________________
Chief Executive Officer (or duly authorized representative)
Olin Corporation
DOCUMENT
CERTIFICATION
I have personally examined and am familiar with the information submitted in this document and all attachments thereto, and I certify, based on reasonable investigation, including my inquiry of those individuals responsible for obtaining the information, that the submitted information is true, accurate and complete to the best of my knowledge and belief. I understand that any false statement made in the submitted information is punishable as a criminal offense under §53a-157b of the Connecticut General Statutes and any other applicable law.
_______________________________________________
Malcolm Pirnie, Inc.
Responsible for document preparation
Olin Corporation (Olin) submitted the Supplemental Investigation Report & Remedial Action Plan Non-Public Properties Study Area Hamden, Connecticut (SI) at the request of the Connecticut Department of Environmental Protection (CTDEP) on March 23, 2005 with the realization that an addendum would be prepared to document the two additional rounds of groundwater sampling and characterization at locations that were not accessible due to winter conditions. Third and fourth quarter rounds of groundwater monitoring were performed in May and August, 2005. The results from these monitoring events were reported to affected property owners as individual reports and to CTDEP as an addendum in October 2005. Olin continued its soil investigation during May 23 – 26, 2005 on 48 properties. Olin had not previously drilled borings on 19 of these properties. The data from the May 2005 sampling event were submitted to the CTDEP and affected property owners in the form of individual property reports during July 2005. On November 10, 2005, the CTDEP issued comments to Olin Corporation on the Department’s review of the SI report. Malcolm Pirnie, Inc., on behalf of Olin, has prepared this Addendum Report to incorporate the results of the May 2005 sampling event into the Conceptual Site Model (CSM) and findings for the Site.
The Supplemental Investigation Work Plan and the SI report should be consulted regarding the initial CSM, including the descriptions of contiguous fill areas, definitions of terms, data quality objectives, and the scope of work. This addendum report is principally concerned with refining aspects of the CSM regarding the presence and extent of isolated fill. Therefore, it includes the following revised elements:
· Graphical presentation of the edge of contiguous and isolated fill areas.
· Tabular and graphical summaries of documentary, field, and historical data regarding isolated fill.
· Tabular presentation of field and laboratory analytical data.
· Tabular and graphical summary of properties where no fill was found.
These elements were evaluated together to update the CSM and conclusions with minor refinements, where necessary, for the Non-Public Properties Study Area.
As a signatory to the Consent
Order, the Town of
The data quality objectives (DQOs) remain the same as detailed in the March 2005 SI Report. That report described the iterative process used to identify and delineate contiguous and isolated fill areas and to characterize the fill for substances of concern (SOCs). In this case the data quality objective is spatial.
These DQOs were addressed through research into site history, interviews with knowledgeable individuals (including property owners), historic maps, photographs, correspondence, reports, and field work. Only the edge of fill must be mapped on a parcel-specific scale so that the degree of contiguous fill at any given parcel can be predicted and remedial decisions can be made for each separately owned parcel of the study area. The same parcel-specific DQO is needed for finding and characterizing isolated fill areas because of the general absence of detailed historical documentation and their presumed smaller extent. This information is summarized in the March 2005 SI Report, revised in the following sections, and evaluated to determine if there is enough information of sufficient detail or quality to meet the objectives.
Aside from one property where access was not granted and subsurface conditions could not be inferred, the CSM is considered complete and representative of conditions. Data from various sources are in agreement and successfully predict the observed conditions. The DQOs resolved the data gaps such that the problems can be logically explained to the stakeholders, and a remedial action plan can be developed. The remainder of this report presents the scope of work used to meet the DQOs and the updated CSM resulting from the supplemental investigation activities.
This section describes the scope of work conducted during the May 2005 supplemental investigation efforts in accordance with the work plan as modified by the conditional approval letter, the approved Interim Report, and additional requests by CTDEP. At each step in the iterative process, a proposal for additional work was reviewed by CTDEP. Comments were discussed in meetings with CTDEP and work scopes were revised accordingly, resulting in a continuous approval process between the investigators and CTDEP. The descriptions of the field work presented in the March 2005 SI Report are still applicable and are further detailed here in response to CTDEP comments.
Table 2-1 summarizes all investigation activities conducted on each parcel in the NPP study area. The table below summarizes the investigation activities conducted in the NPP study area during May 2005 and total for the project.
|
Summary of Investigation Activities |
||
|
|
May 2005 Field Work |
Total Field Work |
|
Properties Inspected |
* |
290 |
|
Properties Sampled |
48 |
267 |
|
Contiguous Fill Delineation Borings |
14 |
457 |
|
Isolated Fill Delineation Borings |
87 |
413 |
|
Bare Spot Samples Analyzed by XRF |
4 |
167 |
|
Fill Samples Analyzed by XRF |
38 |
193 |
|
Native Soil Samples Analyzed by XRF |
63 |
382 |
|
Total Samples Analyzed by XRF |
105 |
742 |
|
Total Samples Analyzed by Laboratory |
34 |
598 |
|
Total Groundwater Samples Analyzed |
31 |
151 |
* The
properties characterized in May 2005 were inspected before Nov. 2004.
Boring and sample locations from all investigations conducted in the NPP are shown on Sheets 2 and 3. The locations of borings and samples collected as part of Olin’s Supplemental Investigation were plotted on site maps in the field by measuring distances in at least two directions to known landmarks, such as buildings and fence-lines. These locations were accurately transferred into computer (CADD) base maps. The CADD maps were then transferred to a GIS system, which is linked to analytical and stratigraphic data collected at each boring location.
To obtain a more precise delineation of the approximate edge of contiguous fill investigated in previous sampling events, investigations of select properties along the edge (access permitting) were conducted via iterative, shallow subsurface borings. A total of 11 non-public properties were revisited and a total of 14 borings were drilled to further delineate the edge of contiguous fill. These borings were drilled in accordance with the approved Scope of Work outlined in Section 3.2 of the Supplemental Investigation Work Plan dated July 2003, revised January 2004. A total of 10 fill and 13 native soil samples were collected from the 14 borings associated with contiguous fill delineation. All samples were analyzed in the field for metals with an x-ray fluorescence (XRF) device. The results of the XRF field screening are shown in Appendix E. Based on the XRF results and previous site investigation knowledge, three native soil samples were submitted for laboratory analysis for the substances of concern (SOC) listed below. The selected samples had the highest XRF lead concentrations or were from an area not previously characterized. In addition, to augment the characterization of fill in Block T, one fill sample was analyzed by a certified laboratory for the following substances reasonably expected to be found in the contiguous fill:
§ Total and SPLP metals by methods 6010B/7470A and 1312
§ ETPH by method CTETPH
§ PAHs by method 8270C
§ Pest/PCBs by method 8081 (only in areas where filling may have postdated the mid 1930s as described in the Conceptual Site Model)
If ETPH concentrations in samples from around fill pre-dating the mid-1930s were elevated, then these samples were also analyzed for pesticides and PCBs.
Any additional sample with XRF lead concentration exceeding 200 mg/kg was submitted for laboratory analysis of total lead and arsenic. Five fill samples met this criterion.
The locations of the May 2005 borings and the revised edge of fill and fill thickness lines are plotted on Sheets 2 and 3.
The March 2005 SI Report presented the results of the 322 borings drilled at 75 properties and the initial inspections performed on 124 properties outside the known contiguous fill areas. In May, a total of 87 borings were drilled on 38 properties in the NPP study area to better delineate the extent of each area of isolated fill identified in March 2005 SI Report. As previously stated, the iterative process used in January and February 2005 was continued during the May 2005 event. Four borings were typically drilled around and approximately 20 feet away from a boring where isolated fill was identified, with additional borings drilled if necessary in a manner similar to that for transects until the isolated fill area was delineated. Each isolated fill area was delineated to the extent practicable, limited in a few instances by physical features or lack of permission to access a property.
At locations inaccessible to the direct-push rig, borings were advanced in two-foot lengths by manually augering a one-inch diameter core with an acetate liner. The isolated fill borings fully penetrated fill materials, if encountered, and advanced into native soil. All logging, sampling, and screening procedures used for direct-push borings were used with the hand augered borings. Due to smaller diameter core, sample size was sometimes smaller, particularly in cores with low recovery.
As part of the investigation outside the known contiguous fill areas, additional borings were drilled in five surface depressions and in two areas where “debris” was reported. Isolated fill was found in three of the surface depressions, but not at the “debris” areas. These areas were subsequently delineated according to the iterative process previously described.
The materials encountered were evaluated for color, odor, and texture and field screened for concentrations of volatile organics using a photoionization device. One sample was collected from a 2-foot interval in each boring and field screened using XRF. The results of the XRF field screening are presented in Appendix E. Samples were selected for laboratory analysis that had the highest XRF lead concentrations or were from an area not previously characterized. Based on the XRF results and previous site investigation knowledge, seven isolated fill samples were submitted for laboratory analysis for total and SPLP metals, ETPH, and SVOCs. Any additional soil sample with XRF lead concentration exceeding 200 mg/kg was submitted for laboratory analysis of total lead and arsenic. Eleven isolated fill samples met this criterion.
The locations of the May 2005 borings and the revised edge of isolated fill lines are plotted on Sheets 2 and 3.
As discussed in section 2.2.2 of the March 2005 SI Report, CTDEP requested that bare spots overlying isolated fill areas be sampled and analyzed in the field by XRF. Four of these bare spots could not be sampled during January and February 2005 due to snow cover. During May 2005, these bare spot samples were field screened by XRF and two samples were submitted to the approved laboratory for PAH, as well as total and SPLP lead and arsenic analyses.
A total of 31 wells (29 new wells and 2 existing wells) were sampled during the four quarterly rounds of groundwater sampling completed by August 2005 as part of the NPP groundwater investigation. All of the wells were sampled in accordance with the QAPP with the exception of E2001D. This well is screened in bedrock and exhibited a very slow recharge rate and substantial draw-down during low-flow purging. Sample turbidity did not stabilize or fall below 5 NTUs. Consequently, the metals samples from E2001D were filtered using a 0.45-micron filter during both the November 2004 and February 2005 rounds. Two existing wells (MS-109-MW and WIN-1067-MW) also could not be sampled in accordance with the QAPP because they contained insufficient water for sampling. After several attempts to purge these wells at a low-flow rate (100 ml/min), the wells ran dry and did not recharge sufficiently to collect samples. These wells are very shallow and do not have adequate screen length below the water table. During the four rounds of groundwater monitoring, well MS-109-MW could not be sampled at all, while well WIN-1067-MW was able to be sampled only once, during the May 2005 event.
Well
development purge water, well sampling purge water, and wash water used to
clean and decontaminate well drilling equipment was containerized in 55-gallon
drums for proper off-site treatment/disposal. One batch of purge and decontamination water
was disposed of at United Industrial Services Inc. in
The purpose of the data validation review is to determine the usability of the data generated by the laboratory by evaluating specific quality assurance and quality control (QA/QC) parameters. All laboratory analytical data generated for Olin during the Supplemental Investigation (June 2004 – August 2005) were reviewed by an independent, third-party and evaluated in accordance with the approved project QAPP, and with guidance from the USEPA CLP National Functional Guidelines for Organic and Inorganic Data Review. This review is consistent with the July 2005 CTDEP draft guidance on Reasonable Confidence Protocols (RCPs) for enhanced laboratory QA/QC procedures for analytical methods and reporting. The data validation report for the data collected by Olin from May 2005 is included on CD in Appendix I. This report does not comment on the validity of data collected by other investigators. The specific QA/QC parameters are:
· Laboratory Control Sample (LCS) Spike Recoveries
The evaluation indicates the accuracy and precision of the sample results reported by the laboratory. If standard QA/QC parameters were found to lie outside validation action limits, results for those analytes may be qualified (list of qualifiers may be found in Appendix I) or rejected. For example, in the few instances when holding times were exceeded, appropriate corrective actions were taken by the laboratory and affected data were flagged accordingly (“J” or “R” flag).
According to the data validator, “In summary, the organic and inorganic analyses were performed acceptably and the data quality is good. There does not appear to be a significant sample matrix effect on [SOC] recoveries, and most results are usable as reported, or usable with minor qualification of reported results as estimated in value. Some low level analyte detections are considered external contamination.” Results for the principal SOCs (arsenic, lead, SPLP lead, PAHs, and ETPH) were not significantly qualified with one exception. Benzo(b)fluoranthene and benzo(k)fluoranthene were reported as a combined value as benzo(b)fluoranthene in several samples, due to the matrix effect on resolving the analytes. This creates a falsely high result for the former and falsely low result for the latter. Therefore, the results for those two compounds in the affected samples are considered as estimated (“J”), with those stated biases. The CTDEP RSR criteria are more strict for benzo(b)fluoranthene, so the reported bias occurs in a more conservative direction. The combined values reported as benzo(b)fluoranthene in some of the affected samples exceed the RSR criteria, whereas they may not have been if the compounds had resolved.
The data validation reports confirm that the QA/QC procedures for the Supplemental Investigation followed during field sampling and in the laboratory produced reliable results according to the data quality objectives established in the work plan. None of the qualified data affect the findings presented in this report. Data generated by other investigators are presented in this report for information only. No assumption is made as to the validity or quality of those data. However, given the magnitude of data collected as a result of the Initial and Supplemental Investigations, there are no significant data gaps that affect the overall conclusions and recommendations of this report.
Development of a CSM is an iterative process. Available data are evaluated to develop an initial hypothesis and identify data gaps. As new data are collected and data gaps filled, the CSM is refined and revised as necessary. The goal of each round of investigation activities was to address data gaps remaining after the previous round, and to modify the CSM based on the results. The data gaps addressed in the May 2005 investigation were associated with delineating and/or confirming a few areas of isolated fill and minor portions of the edge of contiguous fill. The basic CSM presented in the Supplemental Investigation Report (March 2005) remains intact and is only slightly modified following the May 2005 event. These modifications are presented below. Stratigraphic data and the location of the source information for the 101 new borings are summarized in a supplement to Appendix C. A summary of the 34 soil/fill sample analyses and the analytical results are provided in supplements to Appendices G and H, respectively.
During the quality review portion of the iterative process used to delineate the areas of contiguous fill within the NPP study area, eleven properties were identified as requiring further investigation. During the May 2005 event, a total of 14 borings were drilled to further refine the delineation of contiguous fill. Based on the results of these borings, the contiguous fill delineation was revised. These revisions are discussed below by block, contiguous fill area, and property address. The revised contiguous fill delineations are depicted on revised Sheets 2, 3, 4, 5, and 10. Revised analytical data summaries are presented in Tables 3-2, 3-3, and 3-5.
One boring was drilled along the western boundary of the
property to confirm that the contiguous fill previously delineated did not
extend south of the retaining wall along the
Two borings were drilled along the western boundary of the property to verify the contiguous fill line along the western portion of the property. Disturbed soil fill was identified within the western portion of the property to a depth of up to 2.4 feet and the contiguous fill line was revised accordingly, as shown on Sheet 2.
Borings were drilled along the northern boundary of each of these properties to complete transects from the adjacent property (17 Edwards Street). No fill material was found on either property, confirming the fill line previously delineated, as shown on Sheet 2.
Borings were drilled along the southern boundary of each property to complete transects from adjacent properties and to investigate the presence of fill within the southern portion of these properties. No fill material was found on either property and the contiguous fill delineation was revised accordingly, as shown on Sheet 2.
An additional transect was drilled along the northern boundary to further delineate the contiguous fill to the north. One boring in the northeastern corner of the property found fill material to a depth of 1.1 feet confirming the fill line previously delineated, as shown on Sheet 2.
One boring was drilled along the western boundary of the property to complete a transect from the adjacent property and to refine delineation of contiguous fill to the west. No fill material was found on the property, and the contiguous fill line was revised accordingly, as shown on Sheet 2.
Two borings were drilled within the northern portion of the property to delineate contiguous fill in the northern portion of the property. Disturbed soil fill was found to a depth of 3.1 feet, resulting in a revision to the 4-foot fill contour, as shown on Sheet 3.
Two borings were drilled within the western portion of each
property to better delineate the 4 and 10-foot contour lines in the western
portion of the contiguous fill area. The
results show fill was found to a maximum depth of 6 feet in the western portion
of
One of the objectives of the Supplemental Investigation was to investigate portions of the NPP study area outside areas of contiguous fill where smaller, isolated areas of filling may be present. The March 2005 SI Report identified 33 isolated fill areas, encompassing a total of approximately 3 acres in 10 blocks within the NPP Study Area. The total estimated volume of isolated fill was approximately 8,500 yd3 with an average depth of 1.8 feet.
Due to access issues and the inability to advance hand auger borings through frozen ground, not all isolated fill areas were adequately delineated when the Supplemental Investigation Report was submitted in March 2005. However, delineation of these areas was successfully completed during the May 2005 sampling event using the iterative process and scope of work described in Section 2.2. Revised delineation boundaries are shown on Sheets 2 and 3. The rationale for investigation of each property located outside the contiguous fill areas is summarized in Table 3-9. Descriptions of each isolated fill boring drilled in May 2005 are presented in Table 3-10. The vast majority of isolated fill observed in the borings consists of disturbed soil fill less than two feet thick, underlain by native sands. Specifically, the composition is typically reworked sand with minor or trace amounts of rock, ash, slag, glass, coal, ceramic, concrete, and/or brick; or processed sand and gravel (traprock), especially in the rights-of-way. Most of the “debris” reported by owners/tenants also consists of these materials. In a few instances the fill was deeper than 2 feet and/or consisted of refuse or waste fill. Fill found in rights-of-way and under roads may be associated with road building/grading and utility installation rather than an extension of fill from the adjacent properties.
Based on the revised delineation resulting from the May 2005 field work, the total area of isolated fill areas is still approximately 3 acres. Minimum total volume is approximately 9,000 yd3 (a 6% increase from the March 2005 SI Report) with an average fill depth of 2.5 feet (based on borings penetrating fill). Appendix F presents calculations of the volume for each isolated fill area. Isolated fill areas were not found in blocks A, C, F, J, and L.
Laboratory analyses and the resulting analytical data for the soil and fill samples collected in May 2005 are tabulated in Appendices G and H. The raw laboratory data reports are included in Appendix I. Analytical data summaries for each SOC analyzed, detected, and/or exceeding RSR criteria are presented in Table 3-6 for the isolated fill areas. The samples are categorized into those in fill, soil underlying fill, and soil adjacent to fill, which is defined as within 25 feet of the edge of fill. Samples more than 25 feet from a mapped fill area are categorized as ambient samples, which are summarized in Table 3-7. The adjacent and ambient soil samples are mostly surficial (0 to 0.5 feet deep) or shallow (0 to 2 feet deep) sand and typically incorporate surficial topsoil. (Table 3-7 includes 3 samples apparently of disturbed soil fill collected by CTDEP from rights-of-way borings 168-MOR, 303-MS, and 304-MS.) These samples characterize the presence of SOCs that may have migrated to or accumulated within the topsoil from any number of potential sources besides filling.
Sheets 4 and 5 present seven maps of the Study Area displaying the locations and concentration ranges in fill and soil, respectively of the principal SOCs arsenic, lead, SPLP (including TCLP) lead, benzo(a)pyrene (representative of PAHs), and ETPH (including TPH), as well as overall compliance with the RDEC and GAPMC for any substance. Inspection of the complete data set shows that the principal SOCs are the most common substances exceeding RSR criteria and essentially define the scope of the non-compliance. Overall, the most widespread non-compliant SOCs are lead and SPLP lead, with 54 of 113 and 42 of 59 isolated fill sample analyses exceeding RDEC and GAPMC, respectively (Table 3-6). Adjacent soil samples are mostly affected by SPLP lead (10 of 47 analyses exceed GAPMC), with a few total lead and arsenic, SPLP antimony and arsenic, and PAHs also exceeding RSR criteria. These same SOCs are commonly detected in ambient soil samples as well.
Updated descriptions of individual isolated fill areas investigated in May 2005 are presented below.
Block E
Two isolated fill deposits in Block E designated E01 and E02 were delineated further and are discussed separately below.
E01
Isolated fill area E01 is located in the central portion of
block E. It is located behind the garage
at the rear of
Three samples were analyzed for SOCs and all three exceed the
RDEC for lead of 400 mg/kg (E1055S1 at 447 mg/kg, E1034S1 at 3,040 mg/kg, and
E1062S1 at 524 mg/kg). Sample E1034S1
also exceeds GAPMC for SPLP lead and antimony.
Two adjacent soil samples (E1005S1 22.6 ug/l and E1057S1 18.3 ug/l) also
exceed the GAPMC for SPLP lead. No other
RSR criteria were exceeded in samples from within or adjacent to E01.
E02
Isolated fill area E02 is located in the central portion of
block E just southeast of isolated fill area E01 and underlies the rear of the
property at
Two samples were analyzed for SOCs. One sample exceeds the RDEC for lead (E1050S1
475 mg/kg) and both exceed the GAPMC for SPLP lead. Sample E1035S1 also exceeds the GAPMC for
SPLP cadmium. One adjacent soil sample
(E1057S1), which lies between this fill area and area E01, also exceeds the
GAPMC for SPLP lead. No other RSR
criteria were exceeded in samples from within or adjacent to E02.
Block H
One isolated fill deposit in Block H designated H01 was further delineated and is discussed below.
H01
Isolated fill area H01 is located in the southern portion of
block H. It underlies the southeastern
corner of
Five samples from this fill area were analyzed for SOCs. Two samples exceed RSR criteria: H1072S1 for
SPLP lead; and surface sample H3008S1 for total lead and several PAHs.
Two adjacent soil samples just to the west and south also exceed
RSR criteria: H1073S1 for total and SPLP
arsenic, SPLP lead, and several PAHs; and H3008S1 for total lead and several
PAHs.
Block K
Three isolated fill deposits in Block K designated K01, K05, and K06 were delineated and are discussed separately below. Minor adjustments to the descriptions of areas K02 and K04 are also included.
K01
Isolated fill area K01 is
located in the northern portion of K block.
K01 consists of the area between the eastern portion of
Twenty samples from this fill area were analyzed for SOCs. Two samples exceed the RDEC for arsenic and
12 samples exceed the RDEC for lead. Six
samples exceed GAPMC for SPLP lead, one sample exceeds the GAPMC for SPLP arsenic,
and one sample (K1023S1) exceeds the RDEC and GAPMC for several PAHs.
Eight soil samples from adjacent to the fill area were analyzed
for SOCs. Two adjacent soil samples
(214MORSE-S3 and 214MORSE-S3B) exceed the RDEC for lead (up to 1,800
mg/kg), and three other
adjacent samples (K1064S1, K1038S1, and K1128) exceed the GAPMC for SPLP lead.
K02
Isolated fill area K02 is
located southwest of isolated fill area K01. It underlies a portion of the
southern parking lot at
Twelve samples from this fill area were analyzed for SOCs. Four samples exceed the RDEC for arsenic, 5 samples exceed the RDEC for lead (up to 1,830 mg/kg), and 3 samples exceed the GAPMC for SPLP lead. In addition, RSR criteria were exceeded for ETPH, copper, and dieldrin.
Adjacent and underlying soil samples are compliant with RSR criteria.
K04
Isolated fill area K04 is
located southeast of isolated fill area K01 and west of
Eight samples from this fill area were analyzed for SOCs. All samples exceed the RDEC for lead (up to
2,200 mg/kg), and 3 samples exceed the GAPMC for SPLP lead (up to 219
ug/l). One sample (466NH-HA5-S1) exceeds
the arsenic RDEC.
The lead concentration of 5,600 mg/kg in adjacent soil sample
466NH-HA8-S1 exceeds the RDEC for lead.
Other adjacent samples are compliant with RSR criteria.
K05
Area K05 is located along the right-of-way at the corner of
Two samples from this fill area were analyzed for SOCs. One sample (K1122S1) exceeds the GAPMC for
SPLP lead with a concentration of 42.8 mg/L.
One sample (274 – MOR-S1) exceeds the RDEC and GAPMC for
benzo(b)fluoranthene with a concentration of 2,770 ug/kg.
One adjacent sample was analyzed for SOCs and was compliant with
RSR criteria.
K06
This area has been delineated and underlies the central to
northern portions of two properties at 109 and
Two samples from this fill area were analyzed for SOCs. One sample exceeded the GAPMC for SPLP lead,
and one sample exceeded RSR criteria for total lead and several PAHs.
One sample from adjacent boring K1129 was analyzed for
SOCs. This adjacent sample exceeded the
GAPMC for SPLP lead. All other detected
SOCs were compliant with RSR criteria.
Block M
Two isolated fill deposits in Block M designated M03 and M04 were investigated further and are discussed separately below.
M02
Area M02 is located within the backyard of
One sample from this area (M1030S1) was analyzed for SOCs and
exceeded both RDEC and GAPMC for chlordane.
M03
Isolated fill area M03 is
located within the backyard of
The one sample from this fill area (M1042S1) was analyzed for
SOCs. Concentrations detected in this
sample exceeded the RDEC for arsenic, the RDEC for lead, the GAPMC for SPLP
arsenic and SPLP lead. This sample also exceeded
both the RDEC and GAPMC for several PAHs.
Adjacent soil sample M1044S1, just to the west, was analyzed for
SOCs and is compliant with applicable RSR criteria.
M04
Isolated fill area M04 underlies
the backyards of 241 and 245 Goodrich.
This fill area is delineated by borings to the north, south, and
east. This fill area is separated from
the Southwest Satellite Fill Area by two borings to the north and northwest. In addition, fill material and thicknesses
found within area M04 were not consistent with borings within the contiguous
fill area. This fill area covers approximately 1,780 ft2 and contains an estimated 110 yd3 of fill, based on an average
thickness of 1.7 feet. It has a maximum
depth of 4.5 feet at boring M1049. All
borings within this area penetrated disturbed soil fill composed of sand with
traces of ash and coal.
Four samples from within this fill area were analyzed for
SOCs. All four samples contained
concentrations of lead exceeding the RDEC.
Sample M1048S1 also exceeded the GAPMC for SPLP lead, as well as the
RDEC and GAPMC for several PAHs.
One soil sample (M1003S1) taken from an adjacent boring north of
this area contained a concentration of SPLP lead exceeding the GAPMC. All other adjacent soil samples were
compliant with RSR criteria.
Block N
Two isolated fill
deposits designated N03 and N04 were further delineated in May 2005 and are
discussed separately below.
N03
Isolated fill area N03
underlies the backyards (northern portions) of properties at 199, 203, 207-209,
and
Eight samples from this fill area were analyzed for SOCs. Three samples from within this area contained
concentrations of lead exceeding the RDEC ranging from 411 to 685 mg/kg. The SPLP lead concentration in sample N1018S1
exceeds the GAPMC.
One adjacent soil sample (N1036S1) exceeded the RDEC and GAPMC for
arsenic and lead. Two adjacent soil
samples located to the south and east are compliant with RSR criteria.
N04
Area N04 located in the southwestern corner of 199 Goodrich has
been delineated by borings finding no fill material to the north, east, and
west. The area is bordered to the south
by the limits of the NPP study area. One
CTDEP surficial hand auger sample, HA-2, which found disturbed soil fill
described as “red-brown sand, slag & glass”, defined this area prior to May
2005. Two additional borings drilled in
May 2005 found similar fill material to a maximum depth of 1.9 feet at boring
N1028. This area covers approximately
620 ft2 and
contains an estimated 30 yd3 of fill based on an average thickness of 1.4 ft.
One sample from this area (N1029S1) was analyzed for SOCs and
exceeded the GAPMC for SPLP lead.
Block P
One isolated fill deposit found in Block P, designated P02, was further delineated during May 2005 and is discussed below.
P02
Isolated fill area P02 is
located approximately 20 feet northeast of P01 underlying portions of the
backyards of
Two samples from within the fill area were analyzed for
SOCs. Sample P1039S1 exceeded the RDEC
for arsenic and the GAPMC for SPLP arsenic and lead.
Two adjacent soil samples collected from north of the fill area
are compliant with RSR criteria.
Block Q
Three isolated fill deposits were revisited and delineated during May 2005 in Block Q designated Q01 to Q03. They are discussed separately below.
Q01
Isolated fill area Q01 is
located at
One sample was collected
from within this fill area and analyzed for SOCs. Sample Q1018S1 exceeds the GAPMC for SPLP
lead.
One adjacent soil
sample, Q1042S1, was analyzed for SOCs and is compliant with RSR criteria.
Q02
Area Q02, in the rear of the property at
Two samples from within this fill area were analyzed for
SOCs. One sample, Q1047S1, exceeds the
RDEC for lead. Sample Q1031S1 exceeds
the RDEC for arsenic and lead.
One sample collected from adjacent to the fill area was analyzed
for SOCs. This sample, Q1048S1, exceeds
the GAPMC for SPLP lead.
Q03
Area Q03 is located in
the backyard at
One sample from within this fill area was analyzed for SOCs and
exceeded the GAPMC for SPLP lead and chlordane.
One adjacent sample was collected from outside the fill
area. This sample, Q1052S1, was
compliant with RSR criteria.
Block R
One isolated fill deposit found in Block R was further delineated during May 2005. It is designated R01 and is discussed below.
R01
Isolated fill area R01 is
located in the southern portion of block R.
It underlies the rear of properties at
Two samples from within this fill area were analyzed for
SOCs. One sample (R1041S1) exceeds the
GAPMC for SPLP lead, while the second (R1036S1) exceeds the RDEC for arsenic
and the GAPMC for both SPLP arsenic and SPLP lead.
Two adjacent soil samples were analyzed for SOCs and are
compliant with RSR criteria.
Block S
Three isolated fill deposits found in Block S, designated S04 to S06,
were further delineated during May 2005 and are discussed separately below.
S04
Isolated fill area S04 is
located in the southeast corner of
One sample from within
this fill area was analyzed for SOCs.
This sample (S1070S1) exceeded the GAPMC for SPLP lead and RDEC and
GAPMC for several PAHs.
One adjacent soil sample
(S1071S1) was analyzed for SOCs and is compliant with criteria.
S05
Isolated fill area S05 is
located in a shallow topographic depression within the center of block S. Sections of the fill boundary closely match
the existing topographic contour lines.
S05 includes portions of back yards extending from
Eight samples from
within the fill area were analyzed for SOCs.
Two of these samples exceed the RDEC for lead, while two of them exceed
the GAPMC for SPLP lead.
Surrounding samples are
compliant with criteria except for sample S1032S1, which exceeds the GAPMC for
SPLP lead.
S06
Isolated fill area S06 is
located at
One sample collected
from within this fill area (S1016S1) was analyzed for SOCs and exceeded the
RDEC for ETPH, arsenic, lead, and several PAHs.
This sample also exceeded the GAPMC for SPLP lead and several PAHs.
One adjacent sample (S1015S1)
was analyzed for SOCs and also exceeded the RDEC and GAPMC for several PAHs.
Block T
Two isolated fill deposits found in Block T, designated T01 and T04, were
further delineated during May 2005 and are discussed separately below.
T01
Isolated fill area T01 is
located in the northeastern portion of block T.
It underlies portions of properties from 670, 672, and
Four samples collected
from within this fill area were analyzed for SOCs. Three of the four samples were not compliant
with RSR criteria. Two samples (T1077S1,
T1079S1) exceed the RDEC for lead; one sample (T1079S1) exceeds the RDEC for
lead and arsenic, as well as the GAPMC for SPLP lead; and the fourth sample
(T1004S1) exceeds the GAPMC for two pesticides (chlordane and heptachlor
epoxide).
Two adjacent soil
samples were analyzed for SOCs and are compliant with RSR criteria.
T04
Isolated fill area T04 is
located in the northern portion of the property at
One sample (T1027S1) was
collected from within this small fill area and analyzed for SOCs. This sample is compliant with RSR criteria.
In an attempt to delineate
the boundaries of landfilling in the
The CTDEP log for 168-MOR described the boring as:
0 to 1 feet - “black organic”
2 to 8 feet – “reddish brown coarse sand”
Malcolm Pirnie classified the
“black organic” as disturbed soil fill and to confirm or delineate this
potential isolated fill area drilled three borings in the vicinity of
168-MOR. In boring P1013, 1.1 feet of
silty brown sand (disturbed soil fill) was underlain by 0.4 feet of waste fill
underlain by native red-brown medium sand with little silt and some gravel. No fill was found in boring P1037, located in
the right-of-way, and boring P1044 located in the front yard of
The CTDEP log for 303-MS was described as:
0 to 6 inches – dark brown loam, grass
6 inches to 1 foot – dark brown loam
1 to 2 feet – trap rock, basalt (4”)
2 to 8 feet – light brown medium sand.
Malcolm Pirnie classified the upper two feet as disturbed soil fill and to confirm or delineate this potential isolated fill area drilled boring A1059 in the right-of-way in the vicinity of 303-MS and encountered the following stratigraphy:
0 to 0.5 feet – top soil
0.5 to 1.1 feet – gravel and road sub-base
1.1 to 2.1 feet – red brown fine-medium sand, trace fine-medium gravel
2.1 to 3 feet - red brown medium coarse sand, little fine-medium gravel
The CTDEP log for boring 304-MS was described as:
0 to 6 inches – dark brown sand with some organic matter
1 to 3 feet – light brown till - sandy and poorly sorted with some clay
4 to 8 feet – light brown medium sand.
Malcolm Pirnie drilled two borings within 20 feet on either side of boring 304-MS. No fill was found in either boring. Boring J1050 was described as containing:
0 to 1 foot – brown to red brown silty fine – medium sand with trace gravel
1 to 2.1 feet - dark brown medium sand with some fine gravel, subround
2.1 to 3 feet - red brown fine – medium sand.
Boring J1055 had 0.7 feet of topsoil underlain by red brown medium coarse sand with little fine-medium gravel.
The findings from both investigations suggest that localized deposits of disturbed soil fill occur as a result of filling/grading for road construction sub-base. Occasional detections of these materials in the rights-of-way in close proximity to the roadways cannot be inferred to be contiguous.
The initial sampling
program for investigating potential isolated fill areas in the SI Work Plan
selected 49 properties for subsurface borings.
Twenty-eight of these properties were selected to “provide additional
geographic coverage of the NPP study area.”
No fill was found on 18 of these properties. The other properties were selected based on
previous investigations and reports of potential indicators of fill. As a result of the iterative process used during
the whole course of this investigation, over 400 borings were drilled on 102
properties and 35 distinct isolated fill areas were identified covering parts
of 70 properties. All of these isolated
fill areas have been sufficiently delineated.
Data gaps defined in previous reports have been addressed.
The characteristics of
the isolated fill areas suggest that they did not result from the same
systematic filling of the contiguous fill areas by industrial quantities of
waste and refuse fill. Their generally
small size, thinness, scattered locations on elevated land, co-location with
some roadways, and disturbed soil composition (typically with minor coal, white
ash, and non-combustible debris) suggests that they resulted primarily from minor
grading/filling for road construction/maintenance, land development, and/or
post-development disposal of locally derived materials. Such
activity is endemic to historic land use in any older suburban area and would
have taken place regardless of the nearby contiguous filling.
The transition from
agricultural to residential development of the NPP study area began in the late
19th century, when heating with coal was the norm. Domestic garbage and trash was routinely incinerated
in coal-fired home boilers or in back yard burn pits resulting in waste ash
mixed with non-combustible materials (metal, glass, ceramics) that were
commonly buried very locally, typically in low areas of farm fields,
residential backyards, behind outbuildings, or within vegetation along property
lines. This widespread activity resulted
in local deposits of disturbed soil fill with minor amounts of materials and
SOCs similar to those found in the contiguous fill, but unrelated to it.
Mixtures of various borrowed soil, sandy gravel, and crushed stone used
for grading are found in many of the larger isolated fill areas, particularly
underlying the larger formerly commercial parcels or crossing the property
lines of subsequent housing parcels, such as in blocks K and S.
Because they cross many property boundaries, such activity must have
taken place before or in conjunction with land development to make the
topographic grade more suitable for farming or building. Thin deposits of disturbed soil fill with
very local deposits of concentrated ash may represent local domestic disposal
pits subsequent to the development of these areas. They contain minor amounts of materials and
SOCs similar to those found in the contiguous fill, but are unrelated to it.
Roadways and their bordering rights-of-way were originally unpaved, graded locally with fill, and probably routinely tarred or oiled (potentially with coal tar) for dust suppression and covered with ash or cinders to melt snow. Eventually they became pathways for buried utilities and their associated disturbance and filling, and later paved and curbed with crushed stone, asphalt, and concrete. Snowplowing creates a deposit of sand, asphalt fragments, and debris onto the adjacent land. All of these activities result in the presence of disturbed soil with minor amounts of materials and SOCs similar to those found in the contiguous fill but unrelated to it. The asphalt used in paving both roads and driveways throughout the NPP Study Area is believed to be one of the sources of the compounds detected in borings where no fill material was found. Asphalt is produced from the distillation of crude oil or coal tar and is used as the binder mixed with aggregates during the paving process. Asphalt is known to contain several PAHs. Concentrations of benzo(a)pyrene in asphalt range from 0.7 to 3.7 mg/kg for petroleum based asphalt and 2,100 to 15,170 mg/kg for coal tar based asphalt.[1] Samples collected from depths between 0 and 3 feet below grade within the vicinity of asphalt driveways or roads may reflect surficial deposits of pollutants related to asphalting, and should not be used to uniquely identify the presence of fill.
The detailed results from the four rounds of groundwater sampling throughout the NPP study area were presented in the Supplemental Investigation Report and Remedial Action Plan dated March 2005 (November and February rounds), and the addendum to this report dated October 2005 (May and August rounds). From these results, the following general conclusions were made. As the reports stated, the groundwater quality appears to be only slightly degraded relative to upgradient wells. The following SOCs were found in the groundwater above RSR criteria:
§ Chloroform has exceeded groundwater protection criteria (GWPC) in up to 9 wells and exceeds residential groundwater volatilization criterion (RGWVC) at 4 wells. It is not an SOC associated with fill.
§ Extractable total petroleum hydrocarbons (ETPH) were detected at different contiguous fill areas and exceed GWPC at 8 wells.
§ Chlordane and dieldrin exceed GWPC where detected, and the concentrations at upgradient well S2001S exceed their SWPC. These compounds were detected below reporting limits in wells R2001S and NH-499-MW (within fill areas), and the results were estimated (flagged “J”).
§ The zinc concentration at well BT-113 in the Bryden Terrace contiguous fill area exceeds SWPC. Neither location is near the downgradient edge of the site.
§ PAH concentrations in 4 wells, including 2 downgradient wells, slightly exceed their SWPC and detection limit.
Despite detections of SPLP lead above GAPMC in the fill, lead in groundwater is below groundwater protection criteria (GWPC) of the RSR.
Chloroform is listed above as an SOC exceeding GWPC in a maximum of 9 wells throughout the four rounds of sampling, and exceeding RGWVC in 4 wells. Chloroform detections did not appear to consistently correlate to the known fill areas. For example, in the August 2005 sampling round, the highest detected concentrations were within wells K2001S and K2002D (31 ug/l and 48 ug/l, respectively), which are located upgradient of the known fill areas. Additionally, chloroform was not detected in any of the fill samples analyzed for VOCs during the soil investigations within the NPP study area. The source of the chloroform detected in groundwater is unknown, but could be related to releases from public drinking water supplies throughout the NPP study area. Studies since 1974 have concluded that chloroform is one of four VOCs (THMs) that are commonly produced as a by-product of the chlorination treatment process. Chlorine introduced to natural drinking water reacts with the organics within the water to form chlorinated VOCs such as chloroform, dibromochloromethane, bromodichloromethane, and bromoform (Sawyer/McCarty/Parkin, 1994). Thus, it is possible that leaky water mains or over watering from lawn irrigation have introduced chloroform to the surrounding groundwater.
A similar conclusion can be drawn from the detected pesticide concentrations. A maximum of 4 wells contained concentrations of pesticides exceeding RSR criteria. There is no unique correlation between these detected pesticides and the areas of known fill. For example, in the May 2005 sampling event, the highest concentrations of pesticides were detected in well S2001S located upgradient of the Newhall Street Contiguous Fill Area. Chlordane and dieldrin were detected at 0.6 ug/l and 0.39 ug/l, respectively. Both compounds were detected just above the reporting limits of 0.54 ug/l and 0.11 ug/l, respectively. Although concentrations of pesticides were also detected within the fill areas, the upgradient detections within the groundwater suggest no unique correlation to the fill. Similar inconsistencies were found in the soil and fill analysis results as well. Of the 231 total fill samples analyzed for pesticides, a total of 112 (48%) contained detected concentrations of one or more pesticides. Of the 130 native soil samples analyzed for pesticides, 38 (30%) contained detected concentrations of one or more pesticides. This shows that pesticides were detected in both fill and native soil, both inside and outside of known fill areas. The detection of pesticides in both areas suggests that the pesticide residues resulted from activities in both areas unrelated to the filling such as surficial applications to fields, lawns, wetlands (either directly or via runoff), and landscaping.
The Supplemental Investigation accomplished all the objectives set forth in the approved Work Plan and the study area is considered sufficiently characterized to support remedial decisions and remedial design.
With data gathered from 96% of the properties in the study area, the CSM is considered complete and representative of actual conditions. Conclusions for the few properties where access was not granted were inferred from the results from neighboring properties. Data from various sources are in agreement, successfully predicting the presumed conditions, and the results are appropriate for comparison to RSR criteria. The DQOs resolved the data gaps such that conditions can be logically explained to the stakeholders, and a remedial action plan can be chosen.
The nature and extent of the
fill material has been established. With regard to nature, the analytical
results indicate that the contiguous fill and most of the isolated fill areas
have substance concentrations exceeding RSR criteria, including both RDEC and
GAPMC. Non-compliant concentrations are
found throughout the fill volume indicating that any portion has the potential
to exceed RSR criteria. The principal
SOCs (arsenic, lead, SPLP lead, PAHs, and ETPH) are indicators for
non-compliance for the fill because only 7 samples of fill out of 839 samples
are non-compliant only for other SOCs.
The principal SOCs are intrinsic to the fill matrix and occur in all
other fill areas and in all three fill types. However, non-compliant isolated fill was not
found on the following properties:
With regard to extent (quantity and configuration), the five major contiguous fill areas have been mapped in enough detail to locate the edge on any property within about 20 feet and estimate the area, which is approximately 29 acres. The thickness is understood well enough to estimate the volume, which is approximately 300,000 cubic yards. The volume of contiguous fill to a depth of four feet is approximately 150,000 cubic yards.
Thirty-five isolated fill areas were found and most have been mapped to the same precision as the contiguous fill. The total area of isolated fill areas is approximately 3 acres with an average fill thickness of 2.3 feet. Total volume of isolated fill is approximately 9,000 cubic yards.
A thorough review of all the data furnished by the agencies, the other
party’s investigations, Olin’s voluntary Initial Investigation, and Olin’s
Supplemental Investigation, identifies the volume of fill at approximately 309,000
cubic yards in the NPP study area. About
219 properties are at least partially underlain by this fill. The Remedial Action Plan in section 5.0 of
the SI report discusses remediation options to achieve compliance with the
RSR. Sheet 10 has been revised to
indicate which properties in the NPP study area are to be included in the
recommended remedies. The 131 properties
shaded green have some type of fill on at least a portion of the property at
depths generally less than four feet and are recommended to be included in
Alternative 1. The 88 properties shaded
rose have fill present at depths greater than four feet on most of the property
and are recommended to be included in Alternative 2. No need for a remedy has been identified for
the remaining 84 properties. Table 5-10
lists the properties where no fill was found and the justification why a remedy
is not proposed. For the recommended remedy,
which calls for excavation of fill from the contiguous areas down to a maximum depth
of four feet, and excavation of fill from the isolated areas, the estimated
volume of fill to be excavated is approximately 159,000 cubic yards.
[1] Grosenheider,
K. E., et al, “A Review of the
Current Literature Regarding Polycyclic Aromatic Hydrocarbons in Asphalt
Pavement”,